Experimental study and thermodynamic modelling of the B-Fe-Mn ternary system

This work is focused on an experimental study of phase equilibria in the B-Fe-Mn ternary system combined with a CALPHAD theoretical analysis with the aim of creating a reliable theoretical thermodynamic dataset for calculation of the phase diagram of the ternary system. Boron is modelled as an interstitial element in all solid solutions of Fe and Mn. In the experimental study, B-Mn-Fe alloys were prepared and heat-treated at 873 K for 90 days/2160 h and at 1223 K for 60 days/1440 h. Following heat treatment, the phase equilibria and composition of the coexisting phases were determined using scanning electron microscopy and X-ray diffraction analysis. The experimental results obtained, together with experimental results collected from the literature, were used in the optimization of the thermodynamic parameters by using the CALPHAD method. The result of this work is an optimized thermodynamic dataset for the B-Fe-Mn ternary system allowing the phase diagram and thermodynamic properties to be calculated.