Efficient white LEDs with bright green-emitting CsPbBr3 perovskite nanocrystal in mesoporous silica nanoparticles

- CsPbBr3 NCs were incorporated into mesoporous silica with a non-chemical process.
- NCs-MS exhibit excellent optical performance, better thermal and photostability.
- NCs-MS based WLED realizes a facile chromaticity tuning.

Metal-halide perovskites have been hailed as remarkable materials for photovoltaic devices and, recently, their star has also been on the rise in optoelectronics and photonics. Nevertheless, challenging issues, such as the thermal/chemical stability and high-performance devices with long-term stability, limit their practical applications. Here, we successfully prepared CsPbBr3 NCs incorporated into mesoporous silica (NCs-MS) by a simple stirred of MS with CsPbBr3 NCs blended in toluene solution. The resultant NCs-MS nanocomposite exhibit excellent optical performance and good thermal and photostability under illumination of UV light for 120 h. Additionally, NCs-MS nanocomposite is resistant to water, which are beneficial for the fabrication of white light-emitting diode (WLED) devices. Thereby a WLED was constructed by combining NCs-MS nanocomposite with Sr2Si5N8:Eu2+ red phosphor on an InGaN blue chip, achieving a highly efficient luminous efficacy of 47.6 lm/W. Moreover, the WLED also demonstrate wonderful color stability under 120 mA current. This work opens up the exciting opportunity of using all-inorganic CsPbBr3 NCs-MS nanocomposite for high performance and low-cost WLEDs applications.

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