کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5458898 | 1516178 | 2017 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Carbon coated mesoporous Si anode prepared by a partial magnesiothermic reduction for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Owing to its high theoretical capacity, Si based anode materials have been regarded as the most promising alternative anode materials for lithium-ion batteries. Unfortunately, the commercial application of Si based anode materials has been greatly hindered, due to the large volume change of Si materials during their lithiation/delithiation process, which results in severe pulverization, loss of electrical contact and rapid capacity fading. To address these issues, we reported a partial magnesiothermic reduction method by adjusting the proportion of added Mg powder to convert SiO2 into Si/SiO2 and subsequently to coat such a composite with a carbon layer. After removing unreacted SiO2 using HF, carbon-coated mesoporous Si (p-Si@C) can be obtained. The internal pores could accommodate the volume changes of Si and the carbon coating layer could effectively stabilize the interface during cycling. With this design, the as-prepared p-Si@C shows superior electrochemical performance compared with bare Si. When the p-Si@C electrode evaluated at a rate of 0.5Â AÂ gâ1, a reversible capacity of 1146Â mAh gâ1 could still be maintained after 100 cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 716, 5 September 2017, Pages 204-209
Journal: Journal of Alloys and Compounds - Volume 716, 5 September 2017, Pages 204-209
نویسندگان
Lili Wu, Haochen Zhou, Juan Yang, Xiangyang Zhou, Yongpeng Ren, Yang Nie, Song Chen,