کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5459925 | 1516192 | 2017 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Quadrangular-CNT-Fe3O4-C composite based on quadrilateral carbon nanotubes as anode materials for high performance lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Quadrangular-CNT-Fe3O4-C composite based on quadrilateral carbon nanotubes as anode materials for high performance lithium-ion batteries Quadrangular-CNT-Fe3O4-C composite based on quadrilateral carbon nanotubes as anode materials for high performance lithium-ion batteries](/preview/png/5459925.png)
چکیده انگلیسی
A q-CNT-Fe3O4-C composite was synthesized via the homogeneous precipitation of FeOOH nanoparticles on quadrangular carbon nanotubes (q-CNT) substrates. The q-CNT multi-walled carbon nanotube featured one closed end and an open end with a quadrilateral cross section, and the nanotubes were prepared by using co-carbonization method. The FeOOH nanoparticles were encapsulated by amorphous carbon via a hydrothermal treatment and high-temperature calcination of glucose. TEM showed that diameter of the q-CNT was 100Â nm and the tube thickness was 20Â nm. The outer wall of the q-CNT was attached to Fe3O4 with sizes ranging from 80 to 100Â nm via a layer of an amorphous carbon coating. It delivered a specific capacity of 1031.5Â mAh gâ1 after 100 cycles at a current density of 200Â mAÂ gâ1. After 60 cycles, it showed a high specific capacity of 485.6Â mAh gâ1 even at 2000Â mAÂ gâ1. CV and EIS results further suggested that the q-CNT-Fe3O4-C composite exhibited lithium ion uptake/release reversibility and a rapid high current charge/discharge capability. The excellent rate performances of the q-CNT-Fe3O4-C composite can be attributed to the superior electronic transport properties of the quadrilateral CNT with one open end and the synergistic effects of the hybrid components.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 702, 25 April 2017, Pages 499-508
Journal: Journal of Alloys and Compounds - Volume 702, 25 April 2017, Pages 499-508
نویسندگان
Donghui Xu, Guoen Luo, Jingfang Yu, Wenyan Chen, Congcong Zhang, Dong Ouyang, Yueping Fang, Xiaoyuan Yu,