کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5459938 1516192 2017 36 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nano-netlike carbon fibers decorated with highly dispersed CoSe2 nanoparticles as efficient hydrogen evolution electrocatalysts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Nano-netlike carbon fibers decorated with highly dispersed CoSe2 nanoparticles as efficient hydrogen evolution electrocatalysts
چکیده انگلیسی
More active sites and high conductivity are two effective ways to improve the activity of non-noble metal electrocatalysts. Herein, we present a facile electrostatic spinning technique to synthesize highly dispersed CoSe2 nanoparticles on three-dimensional nano-netlike carbon fibers through simple thermal treatment of polyacrylonitrile fibers containing Co ions (Co2+-PANF) and subsequent in-situ selenization. Moreover, we show that the resulting material (denoted as CoSe2-CFN) can serve as highly active, efficient and stable non-precious metal electrocatalyst for HER in acidic media. This material achieves a current density of 10 mA/cm2 at an overpotential of 133 mV with a loading amount of the active material CoSe2 about 0.128 mg/cm2, which is lower than that of the reported CoSe2-based materials. Meanwhile, CoSe2-CFN exhibits excellent catalytic stability for at least 20 h and gives nearly 100% Faradaic yield. The excellent hydrogen evolution reaction performance is due to the highly dispersed CoSe2 nanoparticles providing more active sites as well as the high electrical conductivity of the carbon fibers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 702, 25 April 2017, Pages 611-618
نویسندگان
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