کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5460275 1516191 2017 17 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Multiferroic properties of Ba/Ni co-doped KNbO3 with narrow band-gap
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Multiferroic properties of Ba/Ni co-doped KNbO3 with narrow band-gap
چکیده انگلیسی
In this paper, the influence of Ba/Ni co-doping on the multiferroic properties of (K1−xBax)(Nb1−x/2Nix/2)O3−δ was investigated. A gradual transition from orthorhombic to tetragonal, and to cubic phase with increasing the doping ratio x was observed in the single phase perovskite structure at room temperature. The weakened antiferromagnetism and high ferroelectric polarization with narrow optical band-gaps (1.18-1.84 eV) for x = 0.1-0.3 were observed. Based on the first-principles calculations with GGA+U, we confirm that the Ni: 3d electronic states have a major contribution to the variation of band-gap size and the antiferromagnetic properties. Our results may shed some light on the understanding of the band-gap tuning and multiferroic mechanism in perovskite-type materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 703, 5 May 2017, Pages 67-72
نویسندگان
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