کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5460648 | 1516197 | 2017 | 6 صفحه PDF | دانلود رایگان |
- We prepared CZTS thin films in a simple, low-cost, and environment-friendly manner.
- Highly pure films were prepared using a sol-gel method under mild conditions.
- X-ray diffraction showed that the CZTS had the kesterite structure.
- The calculated optical band gap energy of the films was 1.45Â eV.
To produce the absorber layer material for thin-film solar cells, copper-zinc-tin sulfide Cu2ZnSnS4 (CZTS) thin films were prepared from a sol-gel four-component solution in a simple, inexpensive, and environmentally friendly manner by directly applying it onto a glass substrate in multiple spin-coated layers. Afterwards, the resulting films were thermally processed in a drying oven under circulating air atmosphere without sulfur vapor. The obtained X-ray diffraction peaks exactly matched the CZTS (JCPDS 26â0575) diffraction pattern, indicating that the produced coatings were characterized by the kesterite structure. The calculated optical band gap energy of the obtained films was 1.45Â eV, which was in good agreement with the literature values, thus suggesting their possible use as alternative candidate absorber materials. The obtained SEM images showed that the synthesized densely packed CZTS films with large sphere-like particles were compact and uniform. Therefore, we have shown for the first time in this study that nearly pure CZTS thin films can be obtained from solution through a one-step sol-gel process, which corresponds to non-toxic sulfurization at a relatively low heating temperature and non-vacuum conditions.
Journal: Journal of Alloys and Compounds - Volume 697, 15 March 2017, Pages 361-366