کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5460977 1516201 2017 35 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
First-order magneto-structural transition and magnetocaloric effect in Mn(Co0.96Fe0.04)Ge
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
First-order magneto-structural transition and magnetocaloric effect in Mn(Co0.96Fe0.04)Ge
چکیده انگلیسی
The magnetic properties and magnetic structure of an as-prepared Mn(Co0.96Fe0.04)Ge sample has been investigated by powder neutron diffraction as well as X-ray diffraction and magnetisation measurements. The sample has a ferromagnetic structure in the low-temperature orthorhombic phase and a magneto-structural transition at 299 (1) K to the high-temperature paramagnetic hexagonal phase. This transition occurs at a higher temperature than for as-prepared (Mn0.96Fe0.04)CoGe (TM = 239 (1) K). Increased occupancy by Fe of the Co (4c) site rather than the Mn (4c) site results in this smaller suppression of the structural transition temperature away from that of undoped MnCoGe. It was found that chemical pressure increased the Curie temperature TCorth in the orthorhombic phase from 355 (5) K in Mn(Co0.96Fe0.04)Ge to 379 (6) K in MnCoGe. Mn(Co0.96Fe0.04)Ge exhibits a large magnetocaloric effect around the magneto-structural transition, −ΔSmpeak = 11 (2) J kg−1 K−1 and RC = 187 (30) J kg−1 with μ0ΔH = 5 T. The magneto-structural transition is a first order transition as demonstrated by master curve analysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 693, 5 February 2017, Pages 32-39
نویسندگان
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