کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5463439 | 1517182 | 2017 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The effects of ball milling on microstructures of graphene/Ni composites and their catalytic activity for hydrogen evolution reaction
ترجمه فارسی عنوان
اثر آسیاب توپ بر ریزساختار ترکیبات گرافن / نیکل و فعالیت کاتالیزوری آنها برای واکنش تکامل هیدروژن
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کلمات کلیدی
هیدروژن، آمورف توپ فرز، گرافن،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
چکیده انگلیسی
The effects of the ball milling on microstructures of the graphene/Ni composites and subsequent hydrogen evolution reaction in acidic solution were investigated. Ni nanoparticles with average grain size of 4Â nm were uniformly dispersed on the graphene surface after short time ball milling. While amorphous characteristic was observed due to long time ball milling. The graphene/Ni composites with amorphous structure exhibited higher electrocatalytic performance than the graphene/Ni composites with nanocrystalline structure. The Volmer-Heyrovsky mechanism was found for the graphene/Ni composites with nanocrystalline structure, while the graphene/Ni composites with amorphous structure showed evident Heyrovsky mechanism. The excellent hydrogen evolution reaction and stability of the graphene/Ni composites could be attributed to superior interfacial contact, amorphous Ni, and synergistic effect between amorphous Ni and high conductive graphene.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 206, 1 November 2017, Pages 124-127
Journal: Materials Letters - Volume 206, 1 November 2017, Pages 124-127
نویسندگان
Lv Jinlong, Zhuqing Wang, Hideo Miura,