کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5463557 1517200 2017 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of in-situ high nitrogen-doped helical carbonaceous nanofibers toward high-performance lithium-ion batteries
ترجمه فارسی عنوان
سنتز نانو فیبرهای کربنیک هلیوم نیتروژن بالا به جای باتری های لیتیوم یون با عملکرد بالا
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
چکیده انگلیسی
The great demand for high-power lithium-ion batteries (LIBs) has spurred extensive research on carbonaceous electrode materials. In this work, a novel high nitrogen-doped helical carbonaceous nanofiber derived from pyrolytic resins was fabricated. Helical m-phenylenediamine-formaldehyde resin nanotubes were prepared via a sol-gel duplication method using a chiral amphiphile as the template. Then, the obtained resin nanotubes were subject to carbonize at 600 °C under Ar atmosphere, forming helical carbonaceous nanofibers with N content of 12.4 wt%. The inner tunnels were disappeared owing to the thermal contraction. Wide angle X-ray diffraction and Raman spectrum analysis verify that the obtained nanofibers were amorphous carbon predominantly. The electrochemical characterization reveals that the in-situ nitrogen-doped carbonaceous nanofibers exhibit high specific capacity, together with long cycle time and excellent rate capability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 188, 1 February 2017, Pages 308-311
نویسندگان
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