کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5479488 | 1522087 | 2017 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Efficient removal of organic dyes from aqueous solution by rapid adsorption onto polypyrrole-based composites
ترجمه فارسی عنوان
حذف کارآمد از رنگ های آلی از محلول های آبی با جذب سریع بر روی کامپوزیت های پلی پیررول
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
In order to improve the adsorption capacity of polypyrrole, two inexpensive and renewable biological resources containing abundant functional groups were used to achieve novel polypyrrole-based composites. Three low-cost polypyrrole-based composites, polypyrrole-chitosan-lignosulfonate (PPY-CS-LS), polypyrrole-chitosan (PPY-CS) and polypyrrole-lignosulfonate (PPY-LS) were prepared via an in-situ polymerization of pyrrole monomers with chitosan (CS) and/or lignosulfonate (LS) as dispersants. PPY-CS-LS, PPY-CS and PPY-LS nanoparticles with average diameters of 50 nm, 73 nm and 213 nm, respectively, were obtained with pyrrole/oxidant molar ratio of 1:1, and the contents of CS and/or LS of 10 wt%. Selective adsorption properties of the three composites for six dyes were investigated. Results showed that PPY-CS-LS and PPY-CS composites possessed much higher selectivity for acid (anion) dyes, especially for Congo red (CR); the removal efficiencies of PPY-CS-LS and PPY-CS composites for CR were up to 99.3% and 95.4%, respectively, when the initial concentration of CR was 60 mg Lâ1 at the adsorption temperature of 30 °C. The adsorption equilibrium time for CR was 30 min, which was more rapid than those of other reported PPY-based adsorbents. The results suggested that the PPY-CS-LS composite exhibited a high adsorption performance for dyes because of the synergistic effects of amino/hydroxyl-containing functional groups from CS, sulfonic groups from LS, and nitrogen-containing functional groups from PPY chains. Furthermore, the adsorption processes were feasible and spontaneous. Therefore, a productive route to fabrication of low-cost PPY-based composite nanoparticles with controllable size and high dye adsorption ability was achieved.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Cleaner Production - Volume 167, 20 November 2017, Pages 739-748
Journal: Journal of Cleaner Production - Volume 167, 20 November 2017, Pages 739-748
نویسندگان
Jing Zhou, Qiu-Feng Lü, Jia-Jia Luo,