کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
54873 47029 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective synthesis of natural benzaldehyde by hydrolysis of cinnamaldehyde using novel hydrotalcite catalyst
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Selective synthesis of natural benzaldehyde by hydrolysis of cinnamaldehyde using novel hydrotalcite catalyst
چکیده انگلیسی

A novel Al–Mg hydrotalcite catalyst was synthesized by using combustion synthesis with glycerol as fuel. It was fully characterized. It was used in the hydrolysis of cinnamaldehyde to produce natural benzaldehyde. This is the first report of using a heterogeneous hydrotalcite for making natural benzaldehyde. The effects of different parameters on rate of hydrolysis were studied systematically to establish the kinetics of reaction. The reaction follows pseudo first order kinetics at a fixed catalyst loading with apparent activation energy of 10.00 kcal/mol. The reaction is intrinsically kinetically controlled. The maximum conversion obtained at optimum conditions was 70% in 4 h with 100% selectivity towards natural benzaldehyde. The catalyst can be reused several times without loss of activity.Both the catalyst synthesis and application in retro-aldol reaction are novel aspects of the current work.

Figure optionsDownload high-quality image (89 K)Download as PowerPoint slideHighlights
► First report on synthesis of natural benzaldehyde over heterogeneous catalyst.
► Novel method of catalyst synthesis by combustion using glycerol as fuel.
► Reaction of cinnamaldehyde with water in methanol at 130 °C.
► 100% selectivity of natural benzaldehyde.
► The reaction follows pseudo first order kinetics.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 207, 30 May 2013, Pages 162–169
نویسندگان
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