کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5492213 1525146 2016 31 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study the cooperative motion of long-chain polyelectrolyte in presence of small globular protein
ترجمه فارسی عنوان
بررسی حرکت تعاونی پلیا الکترولیت زنجیره طولانی در حضور پروتئین کوچک کروی
کلمات کلیدی
سیستم نامتقارن، پویایی پلیمر، رژیم نیمه دمی مفهوم مقیاس متورم و انقباض زیر ویسکوزیته دینامیکی،
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
چکیده انگلیسی
We study in this paper the effect of small globular protein on the dynamic properties of long-chain NaPSS in semidilute regime using Dynamic Light Scattering and viscometry in three phases respecting the pH of the medium. The scaling concept of the heterogeneous system is compared with the De Gennes argument for homogeneous polymer solutions. The results showed a positive and negative deviations to the De Gennes approach of the correlation length scale of mixture defined by (cc*)δ. The macroscopic viscosity of protein and the potential electrostatic interaction are taken as principal factors affecting the cooperative motion of blobs. δ was discussed as the parameter responsible for the conformational change of polyelectrolyte chain subunit within blob. The theoretical analysis of the electrostatic interaction between protein and subunit gave one possible solution relating the deviation δ to the dimensionless coupling constant u as δ~uu+1 and δ~−13uu+1 for a swollen and shrunk subunit, respectively. A good accordance of experimental values of δ to theoretical approach was found.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volume 503, 15 December 2016, Pages 18-24
نویسندگان
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