Comparison between Cs–Cu/ZrO2 and Cs–Co/ZrO2 catalysts for NOx reduction by toluene

The effect of Cs content in Cs–Cu/ZrO2 and Cs–Co/ZrO2 systems was studied in NOx reduction by toluene. From physicochemical characterization data, it was shown that the formation of CuO crystallites is favoured following the Cs content in Cs–Cu/ZrO2 catalysts whereas cesium tends to hinder the formation of Co3O4 crystallites in Cs–Co/ZrO2. Regarding their catalytic properties, Cs–Cu/ZrO2 catalysts with low Cs content are more active than Cs–Co/ZrO2 ones in NOx reduction by toluene. The difference is partly due to the formation of high NO2 amount over cobalt based catalysts.

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► Influence of Cs content in Cs–Cu/ZrO2 and Cs–Co/ZrO2 systems studied in NOx reduction by toluene.
► Formation of CuO crystallites favoured versus Cs content in Csx–Cuy/ZrO2 catalysts.
► Formation of Co3O4 crystallites hindered in the presence of Cs in Csx–Coy/ZrO2.
► Csx–Cuy/ZrO2 catalysts are more active than Csx–Coy/ZrO2 in NOx reduction by toluene.