کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
55785 | 47063 | 2011 | 4 صفحه PDF | دانلود رایگان |
A highly efficient iron-catalyzed production of 5-hydroxymethylfurfural (HMF) from sugar is reported. The dehydration of fructose and sucrose has been studied in the presence of different iron salts and co-catalysts. As a result, it was found that fructose and sucrose could be efficiently and selectively converted to HMF using a combination of environmentally friendly FeCl3 and tetraethyl ammonium bromide (Et4NBr) as the catalytic system. For instance, 86% HMF yield at full conversion of fructose was obtained for 2 h at 90 °C in air. The effects of catalyst concentration, reaction time and reaction temperature were investigated in detail. The electronic absorption spectra of different catalysts were recorded, and the FeCl3Br− ion was considered as the active catalyst species.
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► Efficient defunctionalization of fructose and sucrose is achieved.
► Catalytic system includes FeCl3 and tetraethyl ammonium bromide.
► Hydroxymethylfurfural is produced from fructose and sucrose.
► The catalyst active species is discussed.
Journal: Catalysis Today - Volume 175, Issue 1, 25 October 2011, Pages 524–527