Fischer–Tropsch synthesis in milli-fixed bed reactor: Comparison with centimetric fixed bed and slurry stirred tank reactors

This paper presents a comparative study of Fischer–Tropsch synthesis in single channel milli-fixed bed, conventional centimetric fixed bed and slurry stirred tank reactors. In the three reactors, the catalytic measurements were carried out with the same conventional platinum-promoted alumina supported cobalt catalyst at 493 K and 20 bar using a stoichiometric syngas ratio (H2/CO = 2). The single channel milli-fixed bed reactor displays a higher initial Fischer–Tropsch reaction rate than the conventional centimetric fixed bed reactor. This effect was assigned to a better temperature control and less significant catalyst deactivation during the startup of the single channel milli-fixed bed reactor. The slurry stirred tank reactor shows much lower hydrocarbon productivity than the milli- and centimetric fixed bed reactors, which is probably due to incomplete catalyst reduction. A considerable catalyst deactivation due to the uncontrolled temperature hike can occur during the reactor startup in the conventional centimetric fixed bed reactor. The slurry stirred tank and milli-fixed bed reactors show similar apparent deactivation behavior.

Figure optionsDownload high-quality image (107 K)Download as PowerPoint slideHighlights
► Single channel milli-fixed bed reactor allows higher initial hydrocarbon productivity in Fischer–Tropsch synthesis than centimetric fixed bed and slurry stirred tank reactors.
► A considerable catalyst deactivation due to the uncontrolled temperature hike can occur during the reactor startup in the centimetric fixed bed reactor.
► Single channel milli-fixed bed, centimetric fixed bed reactor and slurry stirred tank reactors exhibit different initial deactivation behaviors.