کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5748500 | 1619099 | 2017 | 12 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Photo-Fenton-like degradation of Rhodamine B dye from waste water using iron molybdate catalyst under visible light irradiation Photo-Fenton-like degradation of Rhodamine B dye from waste water using iron molybdate catalyst under visible light irradiation](/preview/png/5748500.png)
- Iron molybdate Fe2(MoO4)3 were prepared.
- The morphology was synthesis route dependent.
- Narrow band gap was observed.
- RhB degradation was followed pseudo -first-order kinetics.
- The RhB degradation efficiency was arrived â¼97% at low period.
Iron molybdate Fe2(MoO4)3 nanopowders with different morphologies have been successfully tailored using two different techniques; co-precipitation and sol gel auto-combustion methods Evidently, X-ray diffraction (XRD) profiles manifested that monoclinic Fe2(MoO4)3 with space group P21/a was acquired at different annealing temperatures from 400 to 600 °C for 2 h using both routes. FE-SEM micrographs evidenced that the formed particles was exhibited aggregates of plates staked with different directions for the sample annealed at 400 °C which it was converted to the brain or an array of fused spheres for the samples annealed at 600 °C using co-precipitation strategy. Otherwise, the microstructure of the formed particles was appeared as a homogeneous porous spherical cluster for Fe2(MoO4)3 sample annealed at 400 °C which it was showed a honey comb like for the sample annealed at 600 °C. Overall, Fe2(MoO4)3 nanopowder prepared by co-precipitation method at 400 °C was exhibited the highest photo Fenton catalytic activity with efficiency â¼97% for degradation of RhB dye after 60 min. In this regards, the highest catalytic activity was attributed to the strong absorption of Fe2(MoO4)3 in the visible-light region due to high surface area of the distinct morphologies and generation of reactive OH from H2O2 synergistically activated by both Fe3+ and MoO42â.
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Journal: Environmental Nanotechnology, Monitoring & Management - Volume 8, December 2017, Pages 175-186