Pollutant emissions from the pyrolysis and combustion of viscoelastic memory foam

- Pollutants evolved during thermal degradation of VMF have been studied.
- Nitrogenated semivolatile compounds, in additions to PAHs, have been determined.
- Low toxicity levels were obtained at all experimental conditions.
- Important formation factors of NH3, HCN and NO were detected.

Thermal degradation of viscoelastic memory foam (VMF) in a horizontal laboratory scale reactor has been studied. Pyrolysis and combustion experiments under sub-stoichiometric conditions were performed at four different temperatures (550 °C, 650 °C, 750 °C and 850 °C) for the determination of pollutants. Analyses of gas and semivolatile compounds, including polychlorodibenzo-p-dioxins and furans (PCDD/Fs) and dioxin-like polychlorobiphenyls (dl-PCBs) are shown. From the results, it was deduced that pyrolytic conditions favor the formation of PAHs, methane, ethylene, NH3 and dl-PCBs, whereas the presence of oxygen involves a higher emission of PCDD/Fs and simple N-containing compounds such as NO and HCN. The toxic levels calculated for PAHs, PCDD/Fs and dl-PCBs in all cases were low confirming that the incineration of VMF mattress waste could be a good option for waste management. Nevertheless, relatively high emissions of NO, NH3 and HCN were obtained and their reduction must be considered.

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