کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5761863 | 1624802 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Revealing the structure of bamboo lignin obtained by formic acid delignification at different pressure levels
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم کشاورزی و بیولوژیک
علوم زراعت و اصلاح نباتات
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چکیده انگلیسی
Bamboo was fractionated using formic acid based on a one-step organosolv process under high pressure (at 145 °C for 45 min, 0.3 MPa) and at atmospheric pressure (at 101 °C for 120 min), respectively. High-pressure formic acid lignin, atmospheric formic acid lignin and milled wood lignin of bamboo were subjected to comprehensive structural characterization using gel permeation chromatography (GPC), Fourier transform infrared (FTIR) and solution-state NMR techniques (1H, 13C, 2D-HSQC, and 31P-NMR spectroscopies). The results indicated that the formic acid fractionation under high pressure presents a quick and efficient delignification method by enhancing the cleavage of interunitary bonds in lignin (β-O-4â², β-β and β-5â²), and dissolved lignin also occurred condensation reaction. As compared to atmospheric formic acid lignin, high-pressure formic acid lignin obtained showed higher purity and yield, and had relatively higher contents of phenolic and carboxylic groups.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Industrial Crops and Products - Volume 108, 1 December 2017, Pages 864-871
Journal: Industrial Crops and Products - Volume 108, 1 December 2017, Pages 864-871
نویسندگان
Yongchao Zhang, Qingxi Hou, Wenyang Xu, Menghua Qin, Yingjuan Fu, Zhaojiang Wang, Stefan Willför, Chunlin Xu,