کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5761892 1624802 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and properties of polyester-based polymeric surfactants from diterpenic rosin
ترجمه فارسی عنوان
سنتز و خواص سورفکتانت های پلیمری بر پایه پلی استر از رزین دوترپنیک
کلمات کلیدی
سورفکتانت پلیمری، کلم بروکلی فعالیت سطحی، اموال رئوولوژی، امولسیون
موضوعات مرتبط
علوم زیستی و بیوفناوری علوم کشاورزی و بیولوژیک علوم زراعت و اصلاح نباتات
چکیده انگلیسی
A series of polymeric surfactants, poly acrylic acid rosin polyethylene glycol esters (P-AAR-PEG), have been synthesized from natural diterpenic rosin. Their structures were characterized by Fourier Transform Infrared Spectrometer (FTIR) and their molecular weights were characterized by Gel Permeation Chromatography (GPC). Their critical micelle concentration (CMC), surface tension (γCMC), foaming property (FP), and hydrophile-lipophile balance (HLB) value were evaluated. Their thermal properties were measured by Thermal Gravimetric Analyzer (TGA) and fluid behaviors were studied by Rotational Rheometer. The influence of concentration on the properties of oil-in-water emulsions was examined and contrasted the stability of emulsion by the mean droplet size between day1 and day7. The weight-average molecular weight of P-AAR-PEG ranged from 1770 to 5071. CMC values of P-AAR-PEG were ranged from 0.33 to 0.87 g/L and the corresponding γCMC values were ranged from 37.8 to 39.1 mN/m respectively. Their CMC and γCMC values decreased and then increased with the increment of molecular weight of hydrophile group. Rheological measurements indicated that the P-AAR-PEG solutions changed from pseudoplastic property to Newtonian with increasing shear rate. P-AAR-PEG1000 had good emulsion ability to turpentine in water. When the concentration of P-AAR-PEG1000 was 8 wt%, the emulsion remained stable for more than 7 days.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Industrial Crops and Products - Volume 108, 1 December 2017, Pages 371-378
نویسندگان
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