کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
578918 | 1453138 | 2011 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Size distribution and chemical composition of metalliferous stack emissions in the San Roque petroleum refinery complex, southern Spain
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
We demonstrate that there is great variation in the size range and chemical composition of metalliferous particulate matter (PM) present within petrochemical complex chimney stacks. Cascade impactor PM samples from seven size ranges (17, 14, 5, 2.5, 1.3, 0.67, and 0.33 μm) were collected from inside stacks within the San Roque complex which includes the largest oil refinery in Spain. SEM analysis demonstrates the PM to be mostly carbonaceous and aluminous fly ash and abundant fine metalliferous particles. The metals with the most extreme concentrations averaged over all size ranges were Ni (up to 3295 μg mâ3), Cr (962 μg mâ3), V (638 μg mâ3), Zn (225 μg mâ3), Mo (91 μg mâ3), La (865 μg mâ3), and Co (94 μg mâ3). Most metal PM are strongly concentrated into the finest fraction (<0.33 μm), although emissions from some processes, such as purified terephthallic acid (PTA) production, show coarser size ranges. The fluid catalytic cracking stack shows high concentrations of La (>200 μg mâ3 in PM0.67-1.3), Cr and Ni in a relatively coarse PM size range (0.7-14 μm). Our unique database, directly sampled from chimney stacks, confirms that oil refinery complexes such as San Roque are a potent source of a variety of fine, deeply inhalable metalliferous atmospheric PM emissions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 190, Issues 1â3, 15 June 2011, Pages 713-722
Journal: Journal of Hazardous Materials - Volume 190, Issues 1â3, 15 June 2011, Pages 713-722
نویسندگان
A.M. Sánchez de la Campa, T. Moreno, J. de la Rosa, A. Alastuey, X. Querol,