کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
579944 1453147 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Lead(II) ion selective electrodes with PVC membranes based on two bis-thioureas as ionophores: 1,3-bis(N′-benzoylthioureido)benzene and 1,3-bis(N′-furoylthioureido)benzene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Lead(II) ion selective electrodes with PVC membranes based on two bis-thioureas as ionophores: 1,3-bis(N′-benzoylthioureido)benzene and 1,3-bis(N′-furoylthioureido)benzene
چکیده انگلیسی
Two PVC membrane ion selective electrodes for Pb(II) ion based on two bis-thioureas: 1,3-bis(N′-benzoylthioureido)benzene and 1,3-bis(N′-furoylthioureido)benzene as ionophores, are reported. A first membrane formulated using 1,3-bis(N′-benzoylthioureido)benzene as carrier exhibited a Nernstian response to Pb(II) over a wide concentration range (4.0 × 10−6 to 1.0 × 10−2 M) with a slope of 31.5 ± 1.6 mV/dec. It showed a fast response time (t90% = 14 s) and could be used for 10 weeks without any divergence in potentials. The membrane formulated using 1,3-bis(N′-furoylthioureido)benzene as carrier exhibited a Nernstian response in the concentration range (5.0 × 10−6 to 1.0 × 10−2 M), with a slope of 30.0 ± 1.3 mV/dec. Its response time was t90% = 14 s, and it could be used for 14 weeks without any divergence in potentials. The two proposed potentiometric sensors revealed acceptable selectivities for Pb(II) over a wide variety of other metal ions and could be used in a pH range of 2.2-6.0. Both electrodes were assayed in direct potentiometric determination of lead in soils (10-30 mg/kg range) with very good performance (0.99935 correlation coefficient in the comparison against ICP-MS method).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 181, Issues 1–3, 15 September 2010, Pages 140-146
نویسندگان
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