کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580392 | 1453149 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Recovery of platinum from spent catalysts by liquid-liquid extraction in chloride medium
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This work examines a hydrometallurgical route for processing spent commercial catalysts (Pt and PtSnIn/A2O3) used in Brazilian refineries for recovery of the noble metal with less final wastes generation. Samples were initially pre-oxidized (500 °C, 5 h) in order to eliminate coke. The basis of the present route is the partial dissolution of the pre-oxidized catalyst in aqua-regia. Temperature and time necessary to dissolve all platinum were optimized in order to reduce the operation severity and aluminum solubilization. All platinum and 16-18 wt.% of aluminum were dissolved at 75 °C in 20-25 min. Separation of platinum from the acidic solution was accomplished by solvent extraction. The best extractant (>99 wt.%) was Aliquat 336 (a quaternary ammonium salt) in one stage (A/O phase ratio = 1, v/v). Platinum was stripped (>99.9 wt.%) in one stage (A/O phase ratio = 1, v/v) with aqueous sodium thiosulfate (â¥0.75 mol Lâ1). Black platinum was obtained from this solution via reduction with magnesium or ascorbic acid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 179, Issues 1â3, 15 July 2010, Pages 488-494
Journal: Journal of Hazardous Materials - Volume 179, Issues 1â3, 15 July 2010, Pages 488-494
نویسندگان
Roberta Santos Marinho, Julio Carlos Afonso, José Waldemar Silva Dias da Cunha,