کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580416 | 1453149 | 2010 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A natural sorbent, Luffa cylindrica for the removal of a model basic dye
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
In this work, application of Luffa cylindrica in malachite green (MG) removal from aqueous solution was studied in a batch system. The effect of contact time, pH and temperature on removal of malachite green was also investigated. By the time pH was increased from 3 to 5, the amount of sorbed malachite green also increased. Beyond the pH value of 5, the amount of sorbed malachite green remains constant. The fits of equilibrium sorption data to Langmuir, Freundlich and Dubinin-Radushkevich equations were investigated. Langmuir isotherm exhibited best fit with the experimental data. Monolayer sorption capacity increased with the increasing of temperature. Sorption kinetic was evaluated by pseudo-first-order, pseudo-second-order, Elovich rate equations and intraparticle diffusion models. It was inferred that sorption follows pseudo-second-order kinetic model. Thermodynamic parameters for sorption process were also found out. Spontaneous and endothermic nature of sorption was obtained due to negative value of free energy (ÎG°) and positive value of enthalpy (ÎH°) changes. FTIR analyses were also conducted to confirm the sorption of malachite green onto L. cylindrica.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 179, Issues 1â3, 15 July 2010, Pages 658-664
Journal: Journal of Hazardous Materials - Volume 179, Issues 1â3, 15 July 2010, Pages 658-664
نویسندگان
Aylin AltınıÅık, Emel Gür, YoldaÅ Seki,