کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580551 | 1453152 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effective removal of selenate from aqueous solutions by the Friedel phase
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
This research has demonstrated that the Friedel phase, e.g. a chloride-containing hydrocalumite (Ca2Al(OH)6Cl(H2O)2·mH2O), can rapidly adsorb large amounts of SeO42â (up to 1.37 mmol/g). SeO42â is removed via anionic exchange, as evidenced by the expansion of the d-spacing from 0.78 nm of Cl-hydrocalumite to 0.97-0.98 nm of SeO4-hydrocalumite. The newly formed SeO4-adsorbed hydrocalumite is stable in water at pH 4-13, indicating the strong fixation of selenate within the phase. In contrast, intercalated selenate in the Freidel phase can be recovered by desorbing in the NaCl solution, which can also regenerate and recycle the used adsorbent. The findings in this research strongly suggest that the Friedel phase is a new, environmentally friendly and cost-effective adsorbent to adsorb selenate from wastewater streams and dilute solutions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 176, Issues 1â3, 15 April 2010, Pages 193-198
Journal: Journal of Hazardous Materials - Volume 176, Issues 1â3, 15 April 2010, Pages 193-198
نویسندگان
Yueying Wu, Ying Chi, Hongmei Bai, Guangren Qian, Yali Cao, Jizhi Zhou, Yunfeng Xu, Qiang Liu, Zhi Ping Xu, Shizhang Qiao,