کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580720 | 1453154 | 2010 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Using electrocoagulation for metal and chelant separation from washing solution after EDTA leaching of Pb, Zn and Cd contaminated soil
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Electrocoagulation with an Al sacrificial anode was tested for the separation of chelant and heavy metals from a washing solution obtained after leaching Pb (3200 mg kgâ1), Zn (1100 mg kgâ1), and Cd (21 mg kgâ1) contaminated soil with EDTA. In the electrochemical process, the sacrificial anode corroded to release Al3+ which served as coagulant for precipitation of chelant and metals. A constant current density of 16-128 mA cmâ2 applied between the Al anode and the stainless-steel cathode removed up to 95% Pb, 68% Zn and 66% Cd from the soil washing solution. Approximately half of the initial EDTA remained in the washing solution after treatment, up to 16.3% of the EDTA was adsorbed on Al coagulant and precipitated, the rest of the EDTA was degraded by anodic oxidation. In a separate laboratory-scale remediation experiment, we leached a soil with 40 mmol EDTA per kg of soil and reused the washing solution (after electrocoagulation) in a closed loop. It removed 53% of Pb, 26% of Zn and 52% of Cd from the soil. The discharge solution was clear and colourless, with pH 7.52 and 170 mg Lâ1 Pb, 50 mg Lâ1 Zn, 1.5 mg Lâ1 Cd and 11 mM EDTA.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 174, Issues 1â3, 15 February 2010, Pages 670-678
Journal: Journal of Hazardous Materials - Volume 174, Issues 1â3, 15 February 2010, Pages 670-678
نویسندگان
Maja Pociecha, Domen Lestan,