کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580760 | 1453156 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Extraction of cadmium from dilute solution using supported liquid membrane
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
The extraction efficiencies of three phosphoric acid derivatives (D2EHPA, PC-88A and Cyanex 272) for Cd in supported liquid membrane (SLM) have been reported. The equilibrium study indicated the release of two moles of H+ ions from the extractant for extraction of one mole of cadmium ion and association of two moles of the extractants in the extracted species in each case. The diffusion constant of Cd-D2EHPA, Cd-PC-88A and Cd-Cyanex 272 complex through the membrane phase was found to be 2.53Â ÃÂ 10â9, 5.435Â ÃÂ 10â9 and 11.22Â ÃÂ 10â9Â m2/s, respectively. The effects of various parameters such as flow rate, pH of feed solution, concentration of extractants in membrane phase, concentration of H2SO4 in strip solution and concentration of Cd in feed solution on cadmium flux (JCd) have been investigated. At pH 7.5, the percentage of cadmium extraction was found to be maximum with 600Â mol/m3 D2EHPA and PC-88A and 800Â mol/m3 Cyanex 272. The extraction of cadmium using the phosphoric acid derivative follows the order D2EHPAÂ >Â PC-88AÂ >Â Cyanex 272.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 172, Issues 2â3, 30 December 2009, Pages 773-779
Journal: Journal of Hazardous Materials - Volume 172, Issues 2â3, 30 December 2009, Pages 773-779
نویسندگان
P.K. Parhi, N.N. Das, K. Sarangi,