کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
580892 | 1453151 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of calcination on the adsorptive removal of phosphate by Zn-Al layered double hydroxides from excess sludge liquor
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
The influence of calcination of Zn-Al layered double hydroxides (LDHs) on their phosphate adsorption capacity was studied in order to improve phosphorus removal from an excess sludge liquor. Powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), thermogravimetry-differential scanning calorimetry (TG-DSC) and nitrogen adsorption-desorption were employed to characterize the raw Zn-Al and the calcined products. The results reveal that the Zn-Al LDHs evolved to a phase of mixed metal oxides with the calcination temperature increasing to 300 °C and finally to spinel ZnAl2O4 at 600 °C. When the Zn-Al was calcined at 300 °C, the interlayer carbonate ions were removed and the greatest BET surface area of 81.20 m2/g was achieved. The tested phosphate adsorption capacities of the raw and calcined Zn-Al were closely related to the evolution of physicochemical properties of the LDHs during the calcination. The Zn-Al-300 (Zn-Al LDHs calcined at 300 °C) exhibited the highest P uptake of 41.26 mg P/g in 24 h. The phosphate adsorption by the raw Zn-Al and the Zn-Al-300 both follows a pseudo-second-order kinetic model; the adsorption isotherms show a good fit with a Langmuir-type equation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 177, Issues 1â3, 15 May 2010, Pages 516-523
Journal: Journal of Hazardous Materials - Volume 177, Issues 1â3, 15 May 2010, Pages 516-523
نویسندگان
Xiang Cheng, Xinrui Huang, Xingzu Wang, Dezhi Sun,