کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
581146 | 1453157 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Capturing 1,3-butadiene by the highly ordered Al-containing SBA-15
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Capturing 1,3-butadiene by the highly ordered Al-containing SBA-15 Capturing 1,3-butadiene by the highly ordered Al-containing SBA-15](/preview/png/581146.png)
چکیده انگلیسی
This investigation examined the instantaneous adsorption of 1,3-butadiene by aluminum-modified mesoporous silica SBA-15 at ambient temperature. To efficiently trap the 1,3-butadiene pollutant in environment, alumina was incorporated in SBA-15 through various pathways such as one-pot synthesis, solid state grinding and impregnation, and the property-function relation of resulting composites were characterized with XRD, N2 adsorption-desorption, FTIR and NH3-TPD techniques. Adsorption of N-nitrosopyrrolidine (NPYR) was employed for the first time to reveal the difference between the mesoporous silica with the same Al-content but prepared with different methods, providing a potential method for the delicate characterization. Modification with alumina significantly increased the capability of SBA-15 to adsorb 1,3-butadiene, and the one-pot synthesized sample exhibited a higher activity than the post-modified samples, resulting from the formation of Brønsted acidic sites and reservation of silianol groups on SBA-15 host.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 171, Issues 1â3, 15 November 2009, Pages 378-385
Journal: Journal of Hazardous Materials - Volume 171, Issues 1â3, 15 November 2009, Pages 378-385
نویسندگان
Ling Gao, Fang Na Gu, Yu Zhou, Jing Yang, Ying Wang, Jian Hua Zhu,