کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
581435 | 877843 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An oilwell cement slurry additivated with bisphenol diglycidil ether/isophoronediamine-Kinetic analysis and multivariate modelings at slurry/HCl interfaces
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: An oilwell cement slurry additivated with bisphenol diglycidil ether/isophoronediamine-Kinetic analysis and multivariate modelings at slurry/HCl interfaces An oilwell cement slurry additivated with bisphenol diglycidil ether/isophoronediamine-Kinetic analysis and multivariate modelings at slurry/HCl interfaces](/preview/png/581435.png)
چکیده انگلیسی
Loss of zonal isolation in oilwell cementing operations leads to safety and environmental problems. The use of new cement slurries can help to solve this problem. In this paper, an epoxy-modified cement slurry was synthesized and characterized. The features of the modified slurries were evaluated in relation to a standard cement slurry (w/c = 0.50). A kinetic study of HCl interaction with the slurries was carried out using cubic molds. The Avrami kinetic model appears to be the most efficient in describing kinetic isotherms obtained from 25 to 55 °C. Type of slurry, HCl concentration and temperature effects were also evaluated in HCl adsorption onto cement slurries considering a 23 full factorial design. From the statistical analysis, it is inferred that the factor “HCl concentration” has shown a profound influence on the numerical values of the Avrami kinetic constants. However, the best statistical fits were found using binary and tertiary interactive effects. It was found that the epoxy-modified cement slurry presents a good potential to be used in environmental-friendly oilwell operations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 170, Issue 1, 15 October 2009, Pages 374-381
Journal: Journal of Hazardous Materials - Volume 170, Issue 1, 15 October 2009, Pages 374-381
نویسندگان
Antonio R. Cestari, Eunice F.S. Vieira, Andréa M.G. Tavares, Marcos A.S. Jr.,