کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
581999 1453162 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new induction period based reaction rate method for determination trace amounts of phenylhydrazine in water samples
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
A new induction period based reaction rate method for determination trace amounts of phenylhydrazine in water samples
چکیده انگلیسی
A simple, selective, and sensitive kinetic spectrophotometric method is described for the determination of trace amounts of phenylhydrazine, which is based on its inhibition effect on the reaction between meta cresol purple (MCP) and periodate in the presence of bromide ions. The reaction was monitored spectrophotometrically by measuring the change in absorbance of MCP at 525 nm. The calibration graph was linear in the range of 1.0-10.0 μM. The detection limit (3σ) was 0.020 μM. The relative standard deviations for 10 replicate measurements of 3.0, 5.0 and 7.0 μM of phenylhydrazine were 2.0%, 1.4%, and 0.90%, respectively. The potential interfering substances were studied in the presence of phenylhydrazine. The proposed method was applied to the analysis of water samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 166, Issues 2–3, 30 July 2009, Pages 701-705
نویسندگان
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