کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
582886 1453171 2008 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of temperature and initial dibutyl sulfide concentration in chloroform on its oxidation rate by ozone
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
Effect of temperature and initial dibutyl sulfide concentration in chloroform on its oxidation rate by ozone
چکیده انگلیسی
A scheme of dibutyl sulfide (DBS) oxidation with ozone and generation of transitional products was determined in this study. The main identified intermediate product was dibutyl sulfoxide (DBSO), and the main end product of DBS oxidation was dibutyl sulfone (DBSO2). It was determined that for three temperatures: 0, 10 and 20 °C there was certain initial DBS concentration for which half-times observed in experimental conditions were equal and independent from temperature. Generation of phosgene and water as by-products was confirmed for the reaction of DBS with ozone in chloroform. Results of the described study allowed to present generalized mechanism of sulfide oxidation with ozone.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 157, Issues 2–3, 15 September 2008, Pages 319-327
نویسندگان
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