کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
584130 | 1453179 | 2007 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cationic polyelectrolyte/bentonite prepared by ultrasonic technique and its use as adsorbent for Reactive Blue K-GL dye
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
In this study, the cationic polyelectrolyte polyepicholorohydrin-dimethylamine (EPI-DMA) was intercalated into bentonite using ultrasonic. The structure of EPI-DMA/bentonite and its adsorption of Reactive Blue K-GL (RB K-GL) dye were investigated. Compared with raw bentonite, the EPI-DMA/bentonite had larger interlayer spacing and was more hydrophobic, providing with better surface properties for adsorption. The adsorption of RB K-GL on EPI-DMA/bentonite was described by the adsorption models of Langmuir, Freundlich and Dubinin-Radushkevic. The adsorption kinetics was analyzed using pseudo-first- and second-order kinetic models and intraparticle diffusion model. Results showed that both the intraparticle diffusion and first-order adsorption occur in the initial period of adsorption, and that pseudo-second-order kinetic model was more suitable for describing the whole adsorption process. The reaction rates were also calculated. The changes of free energy, enthalpy and entropy of adsorption were evaluated for the adsorption of RB K-GL onto EPI-DMA/bentonite, suggesting that the adsorption process was spontaneous and exothermic.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 147, Issues 1â2, 17 August 2007, Pages 370-380
Journal: Journal of Hazardous Materials - Volume 147, Issues 1â2, 17 August 2007, Pages 370-380
نویسندگان
Qian Li, Qin-Yan Yue, Yuan Su, Bao-Yu Gao, Lin Fu,