کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
59709 1419442 2014 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials
ترجمه فارسی عنوان
کاتالیزور پروتون با کربن فعال و مواد کربنیک نیمه پیلوری شده
کلمات کلیدی
کربن فعال، کربن اکسید شده کاتالیزور اسید جامد، محاسبه کوانتومی شیمیایی، ماده کربنات سولفون شده، کربن فسفرداری شده، ترکیب آلی نیمه پیکری تبدیل کاتالیستی مواد خام بر پایه زیستی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی

The development of environmentally friendly solid acid catalysts is a priority task. Highly oxidized activated carbon and their ion-substituted (saline) forms are effective proton transfer catalysts in esterification, hydrolysis, and dehydration, and thus are promising candidates as solid acid catalysts. Computations by the ab initio method indicated the cause for the enchanced acidity of the carboxylic groups attached to the surface of highly oxidized carbon. The synthesis of phosphorilated carbon was considered, and the proton transfer reactions catalyzed by them in recent studies were analyzed. The development of an amorphous carbon acid catalyst comprising polycyclic carbonaceous (graphene) sheets with –SO3H, –COOH and phenolic type OH-groups was carried out. These new catalysts were synthesized by partial pyrolysis and subsequent sulfonation of carbohydrates, polymers, and other organic compounds. Their high catalytic activities in proton transfere reactions including the processing of bio-based raw materials was demonsrated.

Graphical AbstractProtonogenic functionality of deeply oxidized and phosphated active carbons, as a pyrolized sulphated organic materials determines their catalytic activity in acid base reactions. These materials have well prospective in the field biorefining namely in biomass processing.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 35, Issue 6, June 2014, Pages 815–823
نویسندگان
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