کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
59748 1419423 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction
چکیده انگلیسی

Ni@Pd core-shell nanoparticles with a mean particle size of 8–9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine. Subsequently, the first-ever deposition of Ni@Pd core-shell nanoparticles having different compositions on a metal-organic framework (MIL-101) was accomplished by wet impregnation in n-hexane. The Ni@Pd/MIL-101 materials were characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy and also investigated as catalysts for the hydrogenation of nitrobenzene under mild reaction conditions. At 30 °C and 0.1 MPa of H2 pressure, the Ni@Pd/MIL-101 gives a TOF as high as 375 h−1 for the hydrogenation of nitrobenzene and is applicable to a wide range of substituted nitroarenes. The exceptional performance of this catalyst is believed to result from the significant Ni-Pd interaction in the core-shell structure, together with promotion of the conversions of aromatics by uncoordinated Lewis acidic Cr sites on the MIL-101 support.

Bimetal core-shell Ni@Pd nanoparticles supported on MIL-101 were prepared and exhibit high catalytic activity and selectivity during the reduction of nitroarenes.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 37, Issue 1, January 2016, Pages 91–97
نویسندگان
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