کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
60282 1419469 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Catalytic Performance of Nano-SiO2-Supported Preyssler Heteropolyacid in Esterification of Salicylic Acid with Aliphatic and Benzylic Alcohols
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Catalytic Performance of Nano-SiO2-Supported Preyssler Heteropolyacid in Esterification of Salicylic Acid with Aliphatic and Benzylic Alcohols
چکیده انگلیسی

An efficient and environmentally benign procedure for the catalytic esterification of salicylic acid with aliphatic alcohols, CnH2n+1OH (n = 1–5) and benzylic alcohols, RC6H4CH2OH (R = H, NO2, OCH3, Br, Cl, Me) was developed using nano-SiO2-supported Preyssler heteropolyacid both under thermal conditions and microwave irradiation. Silica nanostructures were obtained through a sol-gel method and were characterized by transmission electron microscopy and powder X-ray diffraction. The effects of various parameters such as solvent type, molar ratio of substrates, Preyssler heteropolyacid loading on silica, catalyst amount, temperature, and reaction time were studied and the optimum conditions were obtained. It has been found that the catalyst with 30 wt% loading is highly active and shows high yields in esterification reactions. The use of nano-SiO2-supported Preyssler heteropolyacid coupled with microwave irradiation allows a solvent-free, rapid (3 min), and high-yielding reaction. This catalyst can be easily recovered and reused for many times without a significant loss in its activity.

An environmentally benign procedure for the catalytic esterification of salicylic acid with alcohols was developed in the presence of nano-SiO2-supported Preyssler heteropolyacid both under thermal conditions and microwave irradiation.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 32, Issue 5, May 2011, Pages 782–788
نویسندگان
, , , , ,