کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
606729 | 1454541 | 2015 | 10 صفحه PDF | دانلود رایگان |

Adsorption is often time consuming due to slow diffusion kinetic. Sizing he adsorbent down might help to accelerate adsorption. For CoFe spinel oxide, a magnetically separable adsorbent, the preparation of nanosheets faces many challenges including phase separation, grain growth and difficulty in preparing two-dimensional materials. In this work, we prepared porous CoFe oxide nanosheet with chemical formula of Co2.698Fe0.302O4 through topochemical transformation of a CoFe precursor, which has a layered double hydroxide (LDH) analogue structure and a large interlayer spacing. The LDH precursor was synthesized from a cheap deep eutectic solvent (DES) system. The calcined Co2.698Fe0.302O4 has small grain size (10–20 nm), nanosheet morphology, and porous structure, which contribute to a large specific surface area of 79.5 m2 g−1. The Co2.698Fe0.302O4 nanosheets show fast removal ability and good adsorption capacity for both organic waste (305 mg g−1 in 5 min for Congo red) and toxic heavy metal ion (5.27 mg g−1 in 30 min for Cr (VI)). Furthermore, the Co2.698Fe0.302O4 can be separated magnetically. Considering the precursor can be prepared through a fast, simple, surfactant-free and high-yield synthetic strategy, this work should have practical significance in fabricating adsorbents.
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Journal: Journal of Colloid and Interface Science - Volume 454, 15 September 2015, Pages 134–143