Intermetallic compounds of Ni and Ga as catalysts for the synthesis of methanol

• We present a study of the formation of supported intermetallic Ni–Ga catalysts.
• Bimetallic phase is formed during a temperature-programmed reduction.
• Formation of the desired phase is demonstrated.
• Effect of calcination conditions on catalyst dispersion and activity is studied.

In this work, we present a detailed study of the formation of supported intermetallic Ni–Ga catalysts for CO2 hydrogenation to methanol. The bimetallic phase is formed during a temperature-programmed reduction of the metal nitrates. By utilizing a combination of characterization techniques, in particular in situ and ex situ X-ray diffraction, in situ X-ray absorption spectroscopy, transmission electron microscopy combined with electron energy loss spectroscopy and X-ray fluorescence, we have studied the formation of intermetallic Ni–Ga catalysts of two compositions: NiGa and Ni5Ga3. These methods demonstrate that the catalysts with the desired intermetallic phase and composition are formed upon reduction in hydrogen and enable us to propose a mechanism of the Ni–Ga nanoparticles formation. By studying the effect of calcination prior to catalyst reduction, we show that the reactivity depends on particle size, which suggests that the reaction is structure sensitive.

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