کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
609970 | 880636 | 2009 | 9 صفحه PDF | دانلود رایگان |
The interactions of bioactive ferulic acid with fumed silica were studied by UV/vis spectroscopy, FT-IR, TPD MS techniques and quantum chemical methods. It was found that surface complexes may form through phenol or carboxyl group of ferulic acid depending on its coverage value. The structure of surface complexes and mechanisms of the ferulic acid chemosorption on the silica surface are discussed. The kinetic parameters of the chemical reactions on silica surface are calculated. The mechanisms of thermal transformations of the ferulic chemosorbed surface complexes are proposed.
Interaction between ferulic acid and silica results in the formation of different energetically favorable surface complexes, which ratio depends on the way of ferulic acid loading (adsorption, mixing or co-milling).Figure optionsDownload as PowerPoint slide
Journal: Journal of Colloid and Interface Science - Volume 339, Issue 1, 1 November 2009, Pages 60–68