کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
610874 880661 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation of polyaniline–metal composite nanospheres by in situ microemulsion polymerization
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Preparation of polyaniline–metal composite nanospheres by in situ microemulsion polymerization
چکیده انگلیسی

Nanosized metal and polyaniline (PANi) composite spheres have been prepared via the polymerization of aniline using PdCl2 or HAuCl4 as the oxidant in a microemulsion system. The oxidization of aniline and the reduction of metal ion happened together during the reaction, yielding PANi and elemental metal simultaneously. The results of FTIR spectra suggested that the oxidation degree of PANi was affected by the initial ratio of metal ions to monomer in the microemulsion system. The PANi–metal nanospheres were characterized using X-ray photoelectron spectroscopy and the conductivity of the composite nanospheres was measured by conventional four-probe method. Scanning and transmission electron microscopy were used to show the morphology of the composites.

Conductive polyaniline–metal composite nanospheres of about 50 nm in diameter, containing dispersed metal nanoparticles of 2–5 nm in size, were prepared in a 1-step oxidative polymerization in microemulsion system.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 326, Issue 1, 1 October 2008, Pages 72–75
نویسندگان
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