کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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611060 | 880665 | 2008 | 4 صفحه PDF | دانلود رایگان |
Alloy catalysts of Pt–Au/C with different Pt/Au ratios were prepared by the precipitation–deposition of metal chlorides and reduced by H2 at 470 K. The surface composition of alloy crystallites deposited on the prepared catalysts was characterized by a technique of temperature-programmed reduction (TPR). In the characterization, O2 was chemisorbed on the reduced catalysts and the chemisorbed O2 was reduced by TPR. A low-temperature routine (LT) in the temperature range between 120 and 430 K was used for the TPR characterization. Monometallic catalysts of Au/C and Pt/C showed a reduction peak in the LT-TPR at reduction temperature (Tr)=145(Tr)=145 and 240 K, respectively. TrTr from alloyed catalysts fell in the range and increased monotonously with their Pt/Au ratios. Interior Pt atoms in deposited alloy particles tended to segregate toward their surface during oxidation treatment at elevated temperatures.
Peak temperatures in the temperature-programmed reduction of PtxAuy/C varied with the surface composition of the alloy catalysts. Interior Pt atoms tended to segregate toward their surface during oxidation at 570 K.Figure optionsDownload as PowerPoint slide
Journal: Journal of Colloid and Interface Science - Volume 325, Issue 1, 1 September 2008, Pages 203–206