کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
611428 | 880675 | 2008 | 11 صفحه PDF | دانلود رایگان |
The intercalation of two cyclic imides, succinimide and glutarimide, in the interlayer spaces of kaolinite was obtained from a “soft guest-displacement method” by displacing previously intercalated guest molecules. The dimethyl sulfoxide (DMSO)–kaolinite preintercalate was particularly efficient for that purpose. The intercalation exchange was done from a concentrated aqueous solution of the cyclic imides, at ambient temperature, in a relatively short time. Complete displacement of DMSO by the cyclic imides was confirmed by the results of several independent characterizations, including XRD, TG/DTA, FTIR, and 13C MAS NMR analyses including dipolar dephasing experiments. The imide intercalates are two dimensionally constrained in the kaolinite interlayer spaces, and are structurally organized in a flattened configuration with their cycle roughly parallel to the ab plane of the kaolinite layers. Elemental analysis gives the following compositions: Al2Si2O5(OH)4⋅(C4H5NO2)0.65 and Al2Si2O5(OH)4⋅(C5H7NO2)0.49, respectively for succinimide and glutarimide. The results of the TG/DTA analyses showed enhanced thermal stabilities of the imide intercalates compared with the starting materials. The intercalation process from the aqueous solution is reversible: in prolonged contact with water, the imide molecules are released, resulting in the rebuilding of the kaolinite structure. These results demonstrate the potential use of kaolinite as a slow-releasing agent for molecules structurally related to the cyclic imides of this study.
The intercalation of two cyclic imides, succinimide and glutarimide, in the interlayer spaces of kaolinite was obtained from a “soft guest-displacement method” by displacing previously intercalated guest molecules. The imide intercalates are two dimensionally constrained in the kaolinite interlayer spaces and are structurally organized in a flattened configuration with their cycle roughly parallel to the ab plane of the kaolinite layers.Figure optionsDownload as PowerPoint slide
Journal: Journal of Colloid and Interface Science - Volume 323, Issue 2, 15 July 2008, Pages 338–348