Optimization of process conditions using response surface methodology for the microwave-assisted transesterification of Jatropha oil with KOH impregnated CaO as catalyst

• We designed a microwave-assisted process for transesterification of Jatropha oil.
• We prepared KOH impregnated CaO as catalyst for transesterification.
• Methanol/oil ratio, catalyst amount and irradiation time have significant effects.
• Optimal operating parameters in this transesterification process were obtained.

A transesterification reaction of Jatropha curcas oil with methanol in the presence of KOH impregnated CaO catalyst was performed in a simple continuous process. The process variables such as methanol/oil molar ratio (X1), amount of catalyst (X2) and total reaction time (X3) were optimized through response surface methodology, using the Box–Behnken model. Within the range of the selected operating conditions, the optimal ratio of methanol to oil, amount of catalyst and total reaction time were found to be 8.42, 3.17% and 67.9 min, respectively. The results showed that the amount of catalyst and total reaction time have significant effects on the transesterification reaction. For the product to be accepted as a biodiesel fuel, its purity must be above 96.5% of alkyl esters. Based on the optimum condition, the predicted biodiesel conversion was 97.6% while the actual experimental value was 97.1%. The above mentioned results demonstrated that the response surface methodology (RSM) based on Box–Behnken model can well predict the optimum condition for the biodiesel production.