کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
620671 882498 2014 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Design and improvement of biodiesel fuels blends by optimization of their molecular structures and compositions
ترجمه فارسی عنوان
طراحی و بهبود سوخت های بیودیزل با بهینه سازی ساختارها و ترکیبات مولکولی آنها مخلوط می شود
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی
Biodiesel is a renewable alternative to petroleum-based diesel fuel that could potentially still prove to be substantially more environmentally friendly than their fossil alternatives. It is obtained by a transesterification reaction from any triglyceride material (edible and non-edible oils, animal fats, lipid algae, etc.) being a potential tool for sustainable development. Its properties as fuel are strongly linked to the molecular structure of its species composition: profile, chemical structure and quantity of fatty acids alkyl esters contained. Hence the manipulation of this composition could lead to improve different kinds of fuel properties. In this work we implement a group contribution approach of the Statistical Associating Fluid Theory, named SAFT-γ to describe the molecular structure of each fatty ester and to evaluate the influence of its chemical framework in the behavior of biodiesel as fuel by predicting the more relevant thermophysical properties. Parameters for the biodiesel model were obtained by experimental data fitting. Optimal fatty ester composition and potential FAMEs profile were obtained by implementing an Evolutionary Genetic Algorithms (EGA). Biodiesel blends found in this work were compared with two commercial B100 stock in order to analyze its thermodynamical behavior which would be a powerful tool for clean combustion analysis differences.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Research and Design - Volume 92, Issue 8, August 2014, Pages 1482-1494
نویسندگان
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