کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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625332 | 1455427 | 2010 | 11 صفحه PDF | دانلود رایگان |
Pretreated fish bones obtained from engraulis European anchovy (Engraulis encrasicolus), European anchovy (Sardine pilchardus), bogue (Boops boops), bluefish (Pomatomus saltatrix) and gilthead seabream (Sparus aurata) were used as natural, cost-effective, waste sorbents for the adsorption and removal of copper from aqueous systems. The removal efficiency of the adsorbent was investigated as a function of pH, contact time, initial metal concentration, temperature, cleaning process, fish species and adsorbent dose. The maximum adsorption capacity was 150.7 mg/g at optimum conditions. The kinetic results of adsorption obeyed a pseudo-second-order model. Copper adsorption fitted the Langmuir isotherm. ΔH0 value was 12.9 kJ/mol indicating that the adsorption mechanism was endothermic. The activation energy, Ea, was determined as 52.9 kJ/mol. Weber–Morris and Urano–Tachikawa diffusion models were also applied to experimental equilibrium data. The fish bones were effectively used as a sorbent for the removal of Cu ions from aqueous solution.
Journal: Desalination - Volume 264, Issues 1–2, 15 December 2010, Pages 37–47