کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
632537 | 1455999 | 2016 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of poly(ether-block-amide)/attapulgite mixed matrix membranes for CO2/N2 separation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Mixed matrix membranes (MMMs) made from selective inorganic fillers and polymers are very attractive in the field of gas separation. But only few of inorganic fillers can simultaneously enhance both gas permeability and selectivity for the pristine polymer membrane. In this work, composite membranes made from poly(ether-block-amide) (Pebax®1657) and attapulgite (ATP) were fabricated. The interaction between ATP nanorods and Pebax matrix were characterized by XRD and FTIR, and the adhesion of MMMs was also examined by SEM. Single gas permeation measurements showed that both the CO2 permeability and CO2/N2 selectivity increased at low ATP loadings (<6.3Â wt%). Compared with the pristine Pebax membrane, the addition of 1.7Â wt% ATP/Pebax MMMs enhanced the CO2 permeability from 56 to 77 Barrer and the CO2/N2 selectivity of from 40 to 52, respectively. In addition, the CO2 permeability and the CO2/N2 selectivity of 1.7Â wt% ATP/Pebax MMMs can be further increased to 104Â Barrer and 84, respectively, as the feeding pressure was increased to 10Â bar. The ATP/Pebax MMMs exhibit well stability, even under the humidified feeding. Overall, ATP/Pebax composite membranes provide a potentially promising alternative for CO2 separation from N2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 500, 15 February 2016, Pages 66-75
Journal: Journal of Membrane Science - Volume 500, 15 February 2016, Pages 66-75
نویسندگان
Long Xiang, Yichang Pan, Gaofeng Zeng, Jinlong Jiang, Jing Chen, Chongqing Wang,