کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
633755 1456043 2014 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Development of rapid thermal processing of tubular cobalt oxide silica membranes for gas separations
ترجمه فارسی عنوان
توسعه عملیات سریع تربیت غشاهای سیلیکا اکسید کبالت لوله ای برای جداسازی گاز
کلمات کلیدی
پردازش سریع سریع سل ژل، غشای سیلیکا، جداسازی گاز، سیلیس اتیل 40
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تصفیه و جداسازی
چکیده انگلیسی


• Scaled up rapid thermal processing (RTP) for thin film silica-derived membranes on tubular supports.
• 6 layers of thin film cobalt oxide silica membranes prepared in less than 12 h.
• Best RTP-membranes based on ethyl silicate 40 precursor and optimized water and nitric acid ratios.
• Best He permeance of 3×10−7 mol m−2 s−1 Pa−1 and He/N2 permselectivity of 69 at 450 °C.

This work shows for the first time that sol–gel derived cobalt oxide silica membranes can be produced on large scale, tubular supports through successful implementation of the rapid thermal processing (RTP) techniques. The combination of fast sol–gel methods and RTP techniques reduced the overall membrane fabrication time from a minimum of 7 days to approximately 12 h. The successful RTP technique was developed by changing the silica precursor from tetraethyl orthosilicate to ethyl silicate 40 and adjusting the nitric acid and water ratios in the sol–gel process. The optimized sol–gel conditions for the best membranes were found to deliver average He permeances of 3×10−7 mol m−2 s−1 Pa−1 and He/N2 permselectivities of 69 at 450 °C. This work has enormous potential for transforming the traditional processing pathways associated with sol–gel derived membranes for both research and commercial separation applications.

High quality, robust rapid thermal processed silica membranes demonstrating excellent He permeance of 3×10−7 mol m−2 s−1 Pa−1 and He/N2 permselectivity of 69 at 450 °C. Figure optionsDownload high-quality image (101 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Membrane Science - Volume 456, 15 April 2014, Pages 192–201
نویسندگان
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