Ni–BaCe0.95Tb0.05O3−δ cermet membranes for hydrogen permeation

BaCe0.95Tb0.05O3−δ (BCTb) proton conducting perovskite powders were first synthesized via an EDTA–CA complexing method. Ni–BCTb cermet membranes were then fabricated by pressing a mixture of the BCTb and Ni powders in a weight ratio of 1:1 at 10 MPa, followed by sintering at 1400 °C for 10 h. The properties of the BCTb powders and the Ni–BCTb membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and conductivity measurement using a 4-probe method. The electrical conductivity of the Ni–BCTb membranes approaches to 400 S cm−1 at room temperature but decreases with increasing temperatures. The maximum hydrogen permeation flux through the asymmetric Ni–BCTb membrane with a 90 μm separation top layer integrated with a porous substrate has reached up to 0.914 mL (STP) cm−2 min−1 at 850 °C when using the 50% H2/N2 mixture feed and He as the sweep gas, respectively. The surface exchange reaction kinetics takes a controlling effect on the hydrogen permeation through the membrane. The long-term operation test indicates that the Ni–BCTb cermet membranes are not sufficiently stable for hydrogen permeation due to the phase decomposition of the BCTb perovskite.

► Asymmetric Ni–BaCe0.95Tb0.05O3−δ cermet membranes are fabricated and characterized.
► Ni–BCTb exhibits a maximum conductivity of 400 S cm−1 at room temperature.
► Maximum hydrogen permeation flux reaches 0.914 mL (STP) cm−2 min−1 at 850 °C.
► Integration of the membrane is retained after the long-term operation.