Influence of thermal history on the cubic-to-hexagonal phase transformation and creep behaviour of Ba0.5Sr0.5Co0.8Fe0.2O3−δ ceramics

The influence of the partial cubic-to-hexagonal phase transformation of Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) on the creep behaviour of this perovskite-type oxygen transport membrane was investigated. Isothermal compressive creep tests were carried out in air in the temperature range 750–950 °C. Arrhenius plots of the creep rate revealed a significant hysteresis effect. During heating, the creep rate changed slightly up to about 850 °C and increased substantially above this temperature. Upon cooling from 950 °C it decreased in a nearly linear manner to temperature. Microstructural investigations support the conclusion that the hysteresis is linked with the growth and transformation kinetics of the hexagonal polymorph at the boundaries of cubic grains of BSCF.

► Creep in isothermal compression in the temperature range 750–950 °C.
► Microstructural aspects and their effect on the creep are discussed.
► Hexagonal polymorph at the boundaries of cubic grains of BSCF.
► Creep hysteresis effect due to hexagonal grain boundary phase.