Design of an effective methanol-blocking membrane with purple membrane for direct methanol fuel cells

In this study, purple membrane (PM) was applied as a methanol-blocking agent on Nafion® membranes. A series of well-organized poly(diallyldimethylammonium chloride)/PM multilayer films were obtained on a Nafion® 212 surface (PDDA/PM/Nafion®) to form composite membranes by the electrostatic layer-by-layer (LbL) self-assembly method. The effect of the PDDA/PM/Nafion® heterogenic interface on proton conductivity and methanol permeability was studied by alternating the deposited surface. With five PDDA/PM bilayers, double-sided modification (PDDA/PM)DF-5 and single-side modification (PDDA/PM)SF-5 resulted in excellent methanol blocking with a 73.4% and 64.7% reduction in methanol permeability in comparison with unmodified Nafion® 212, respectively. Indeed, the involvement of PM suppressed the methanol crossover. With regard to the selectivity factor (PDDA/PM)DF-1 composite membranes showed approximately 2-fold improvement as compared with unmodified Nafion® membranes. The cell performance of (PDDA/PM)SF-1 composite membranes achieved a power density of 27.0 mW cm−2 which is 48.4% increase compared to cells using unmodified Nafion® 212 membranes. Moreover, with (PDDA/PM)DF-1, we achieved a power density of 34.4 mW cm−2. This study highlights the potential application of PM as multifunctional protein membrane in direct methanol fuel cells.

Research highlights▶ PM, a very promising biomaterial, was used as a methanol-blocking agent in DMFCs. ▶ The effect of the PDDA/PM/Nafion® heterogenic interface on proton conductivity and methanol permeability was studied by alternating the deposited surface. ▶ 2 sides of the PDDA/PM multilayers on the substrate have different methanol permeabilities. ▶ The Nafion-based composite membranes exhibit a low methanol permeability and high fuel cell performance.